Xiao Li received her BS degree in polymer materials and engineering from the Wuhan University of Science and Technology, China. She received her PhD degree from Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, China, working on microphase separation of block copolymers for the preparation of antireflective films.
- Liquid crystals (LCs) share the hierarchical structure of crystalline materials and the plasticity of liquids. These properties cause them to be very sensitive to external stimuli, which, in turn, makes LCs uniquely suited to applications such as low-concentration detection. The high sensitivity stems from the fact that, in the presence of different chemical surfaces, LC molecules have different anchoring states such as planar or homeotropic. The boundaries between regions of different anchoring states are regions of high defectivity, a phenomenon that is poorly understood. Dr. Li is designing experimental techniques using patterned polymer surfaces to study the formation of these nanoscopic cores of topological defects, which can be precisely engineered by confining LC on micrometer and nanometer scales.
- In order to enable future technological devices such as semiconductor integrated circuits (ICs), patterned media, and capacitors, lithographic materials and techniques must be extended to the sub-10nm length scale. Block copolymers with high χ values allow for obtaining reduced feature sizes when the molecular weight is small; an example of one such high-χ material is PS-b-PLA. At the same time, PS and PLA blocks have similar surface energies, which means that when a thin film of this material is annealed, neither block segregates to the free surface; instead, a neutrality condition condition exists at the air/ film interface. Dr. Li is working to exploit these two properties of PS-b-PLA to form perpendicular lamellae structures of very small feature size through directed self-assembly.
The Role of Water Volume Fraction on Water Adsorption in Anion Exchange Membranes
Gervasio Zaldivar, Ruilin Dong, Joan M Montes de Oca, Ge Sun, Riccardo Alessandri, Christopher G Arges, Shrayesh N Patel, Paul F Nealey, Juan J de Pablo, Macromolecules, 2025
Role of Crosslinking and Backbone Segmental Dynamics on Ion Transport in Hydrated Anion-Conducting Polyelectrolytes
Zhongyang Wang, Kai Wang, Christopher Eom, Yuxi Chen, Ge Sun, Mincheol Kim, Joan M Montes de Oca, Dongyue Liang, Kushal Bagchi, Shrayesh N Patel, Juan J de Pablo, Paul F Nealey, Advanced Functional Materials, 2025
IEC-Independent Coupling between Water Uptake and Ionic Conductivity in Anion-Conducting Polymer Films
Joan M Montes de Oca, Ruilin Dong, Gervasio Zaldivar, Ge Sun, Zhongyang Wang, Shrayesh N Patel, Paul F Nealey, Juan J de Pablo, Macromolecules, 2025
Water-mediated ion transport in an anion exchange membrane
Zhongyang Wang, Ge Sun, Nicholas HC Lewis, Mrinmay Mandal, Abhishek Sharma, Mincheol Kim, Joan M Montes de Oca, Kai Wang, Aaron Taggart, Alex B Martinson, Paul A Kohl, Andrei Tokmakoff, Shrayesh N Patel, Paul F Nealey, Juan J de Pablo. Nature Communications. 2025.
Directed self-assembly of block copolymer films on atomically-thin graphene chemical patterns
Chang, TH; Xiong, SS; Jacobberger, RM; Mikael, S; Suh, HS; Liu, CC; Geng, DL; Wang, XD; Arnold, MS; Ma, ZQ; Nealey, PF. Directed self-assembly of block copolymer films on atomically-thin graphene chemical patterns. Scientific Reports. 2016. Vol. 6, Pg. 31407.
Directed self-assembly of high-chi block copolymer for nano fabrication of bit patterned media via s
Xiong, S. S. Chapuis, Y. A. Wan, L. Gao, H. Li, X. Ruiz, R. Nealey, P. F.. Directed self-assembly of high-chi block copolymer for nano fabrication of bit patterned media via s. Nanotechnology. 2016. Vol. 27, Pg. 415601.
Directed Self-Assembly of Triblock Copolymer on Chemical Patterns for Sub-10-nm Nanofabrication via
Xiong, SS; Wan, L; Ishida, Y; Chapuis, YA; Craig, GSW; Ruiz, R; Nealey, PF. Directed Self-Assembly of Triblock Copolymer on Chemical Patterns for Sub-10-nm Nanofabrication via. ACS Nano. 2016. Vol. 10, Pg. 7855–7865.
Roadmap on optical metamaterials
Urbas, A. M. Jacob, Z. Dal Negro, L. Engheta, N. Boardman, A. D. Egan, P. Khanikaev, A. B. Menon, V. Ferrera, M. Kinsey, N. DeVault, C. Kim, J. Shalaev, V. Boltasseva, A. Valentine, J. Pfeiffer, C. Grbic, A. Narimanov, E. Zhu, L. X. Fan, S. H. Alu, A. Poutrina, E. Litchinitser, N. M. Noginov, M. A. MacDonald, K. F. Plum, E. Liu, X. Y. Nealey, P. F. Kagan, C. R. Murray, C. B. Pawlak, D. A. Smolyaninov, I. I. Smolyaninova, V. N. Chanda, D.. Roadmap on optical metamaterials. Journal of Optics. Vol. 18, Pg. 093005.
Post-directed-self-assembly membrane fabrication for in situ analysis of block copolymer structures
J Ren, L E Ocola, R Divan, D A Czaplewski, T Segal-Peretz, S Xiong, R J Kline, C G Arges and P F Nealey. Post-directed-self-assembly membrane fabrication for in situ analysis of block copolymer structures. Nanotechnology. 2016. Vol. 27, Pg. 435303.