Xiaosa Zhang received his BS degree in chemistry from Jilin University in China and his MS degree in chemistry from Beijing University of Chemical Technology. Now, he is pursuing his PhD degree under the supervision of Professor Shengxiang Ji at the Changchun Institute of Applied Chemistry of the Chinese Academy of Sciences. He is working on the synthesis and directed assembly of polystyrene-b-Polyester block copolymers with high χ values. He joined the Nealey Group in January 2014 as a visiting student.
Synthesis and self-assembly characteristics of polystyrene-b-polyester block copolymer capable of forming domains as small as 10 nm are very useful for manufacturing a variety of semiconductor devices and next-generation magnetic storage media. Such small domains are possible because this new material has a large Flory−Huggins segment−segment interaction parameter (χ Values), which is nearly six times the χ of poly(styrene-b-methyl methacrylate) (PS-b-PMMA), the most commonly studied polymer for these applications.
Xiaosa synthesized the desired block copolymer using atom transfer radical polymerization (ATRP) and ring-opening polymerization. He is now working on the directed assembly of the synthesized block copolymer on chemically patterned substrates to obtain well-ordered sub-10 nm structures .
The Role of Water Volume Fraction on Water Adsorption in Anion Exchange Membranes
Gervasio Zaldivar, Ruilin Dong, Joan M Montes de Oca, Ge Sun, Riccardo Alessandri, Christopher G Arges, Shrayesh N Patel, Paul F Nealey, Juan J de Pablo, Macromolecules, 2025
Role of Crosslinking and Backbone Segmental Dynamics on Ion Transport in Hydrated Anion-Conducting Polyelectrolytes
Zhongyang Wang, Kai Wang, Christopher Eom, Yuxi Chen, Ge Sun, Mincheol Kim, Joan M Montes de Oca, Dongyue Liang, Kushal Bagchi, Shrayesh N Patel, Juan J de Pablo, Paul F Nealey, Advanced Functional Materials, 2025
IEC-Independent Coupling between Water Uptake and Ionic Conductivity in Anion-Conducting Polymer Films
Joan M Montes de Oca, Ruilin Dong, Gervasio Zaldivar, Ge Sun, Zhongyang Wang, Shrayesh N Patel, Paul F Nealey, Juan J de Pablo, Macromolecules, 2025
Water-mediated ion transport in an anion exchange membrane
Zhongyang Wang, Ge Sun, Nicholas HC Lewis, Mrinmay Mandal, Abhishek Sharma, Mincheol Kim, Joan M Montes de Oca, Kai Wang, Aaron Taggart, Alex B Martinson, Paul A Kohl, Andrei Tokmakoff, Shrayesh N Patel, Paul F Nealey, Juan J de Pablo. Nature Communications. 2025.
Directed self-assembly of block copolymer films on atomically-thin graphene chemical patterns
Chang, TH; Xiong, SS; Jacobberger, RM; Mikael, S; Suh, HS; Liu, CC; Geng, DL; Wang, XD; Arnold, MS; Ma, ZQ; Nealey, PF. Directed self-assembly of block copolymer films on atomically-thin graphene chemical patterns. Scientific Reports. 2016. Vol. 6, Pg. 31407.
Directed self-assembly of high-chi block copolymer for nano fabrication of bit patterned media via s
Xiong, S. S. Chapuis, Y. A. Wan, L. Gao, H. Li, X. Ruiz, R. Nealey, P. F.. Directed self-assembly of high-chi block copolymer for nano fabrication of bit patterned media via s. Nanotechnology. 2016. Vol. 27, Pg. 415601.
Directed Self-Assembly of Triblock Copolymer on Chemical Patterns for Sub-10-nm Nanofabrication via
Xiong, SS; Wan, L; Ishida, Y; Chapuis, YA; Craig, GSW; Ruiz, R; Nealey, PF. Directed Self-Assembly of Triblock Copolymer on Chemical Patterns for Sub-10-nm Nanofabrication via. ACS Nano. 2016. Vol. 10, Pg. 7855–7865.
Roadmap on optical metamaterials
Urbas, A. M. Jacob, Z. Dal Negro, L. Engheta, N. Boardman, A. D. Egan, P. Khanikaev, A. B. Menon, V. Ferrera, M. Kinsey, N. DeVault, C. Kim, J. Shalaev, V. Boltasseva, A. Valentine, J. Pfeiffer, C. Grbic, A. Narimanov, E. Zhu, L. X. Fan, S. H. Alu, A. Poutrina, E. Litchinitser, N. M. Noginov, M. A. MacDonald, K. F. Plum, E. Liu, X. Y. Nealey, P. F. Kagan, C. R. Murray, C. B. Pawlak, D. A. Smolyaninov, I. I. Smolyaninova, V. N. Chanda, D.. Roadmap on optical metamaterials. Journal of Optics. Vol. 18, Pg. 093005.
Post-directed-self-assembly membrane fabrication for in situ analysis of block copolymer structures
J Ren, L E Ocola, R Divan, D A Czaplewski, T Segal-Peretz, S Xiong, R J Kline, C G Arges and P F Nealey. Post-directed-self-assembly membrane fabrication for in situ analysis of block copolymer structures. Nanotechnology. 2016. Vol. 27, Pg. 435303.